PhotoChem Match

Images

Photosensitizer

Chemical Formula: C40H40IrN4

Molecular Weight: 769.01

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 410 nm

Excited-state lifetime

τ: 0.557 µs

Excited-state energy

• E_0,0: 2.17 eV

Emission energy

• E_red: -1.51 V vs. SCE

Oxidation energy

• E_ox: 1.21 V vs. SCE

Excited-state reduction potential

• *E_red: 0.66 V vs. SCE

Excited-state oxidation potential

• *E_ox: -0.96 V vs. SCE

References

• Teegardin, K.; Day, J. I.; Chan, J.; Weaver, J. Advances in Photocatalysis: A Microreview of Visible Light Mediated Ruthenium and Iridium Catalyzed Organic Transformations. Org. Process Res. Dev. 2016, 20 (7), 1156–1163.
• Lowry, M. S.; Hudson, W. R.; Pascal, R. A.; Bernhard, S. Accelerated Luminophore Discovery through Combinatorial Synthesis. J. Am. Chem. Soc. 2004, 126 (43), 14129–14135.
• Slinker, J. D.; Gorodetsky, A. A.; Lowry, M. S.; Wang, J.; Parker, S.; Rohl, R.; Bernhard, S.; Malliaras, G. G. Efficient Yellow Electroluminescence from a Single Layer of a Cyclometalated Iridium Complex. J. Am. Chem. Soc. 2004, 126 (9), 2763–2767.